Type of Document Dissertation Author Li, Congna Author's Email Address email@example.com URN etd-10302004-154714 Title Design and Operating Strategies for Bioreactors Treating Dynamically Varying Concentrations of Gas-Phase Volatile Organic Compounds (VOCs) Degree Doctor of Philosophy (Ph.D.) Department Civil & Environmental Engineering Advisory Committee
Advisor Name Title William M. Moe Committee Chair Donald Dean Adrian Committee Member John H. Pardue Committee Member W. David Constant Committee Member David Spivak Dean's Representative Keywords
- activated carbon
- volatile organic compounds (VOCs)
- sequencing batch biofilter
- air pollution
- load equalization
Date of Defense 2004-09-29 Availability unrestricted AbstractThe dynamically varying concentrations of volatile organic compounds (VOCs) in most waste gas streams present a challenge in design and operation of biofilters treating such off-gases. Studies described in this dissertation were directed toward development and experimental testing of two design modifications/operating strategies that have the potential to improve biofilter performance during unsteady-state loadings.
In the first design modification studied, activated carbon was incorporated into biofilter packing media and a novel periodic operating strategy, Sequencing Batch Biofilter (SBB) operation, was tested under “normal” and various “shock” loading conditions treating methyl ethyl ketone contaminated air. Results demonstrate how the operational flexibility of the SBB system can lead to higher overall removal efficiency and higher minimum instantaneous removal efficiency than are achieved in a conventional continuous flow biofilter (CFB) during transient loading. Denaturing gradient gel electrophoresis of PCR-amplified genes coding for 16S rRNA was used to assess differences in bacterial community structure as a function of height in the SBB and CFB columns. Results suggest that SBB operating strategy can impart a sufficiently large selective pressure to influence microbial community structures.
In the second design modification studied, an activated carbon column was placed in series before a biofilter to assess the potential of the combined system to effectively treat discontinuously loaded VOC mixtures. Abiotic fixed-bed sorption experiments and numerical modeling were conducted to assess the degree of load equalization achieved by GAC columns for gas streams containing intermittent concentrations of acetone and toluene present as single-component contaminants and as a mixture. Performance of the GAC-biofilter integrated system was experimentally evaluated in comparison to a conventional biofilter in treating a mixture of acetone and toluene at various discontinuous loadings. Results demonstrate that load dampening achieved by a passively-operated GAC buffering system can lead to more complete contaminant removal during biofilter treatment. Further, this can minimize diminished performance caused by starvation encountered in conventional biofilters under discontinuous loadings. Because of competitive adsorption, however, the degree of load equalization achieved by a passively operated GAC system for different constituents in multi-contaminant gas streams can vary markedly.
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