Title page for ETD etd-07122006-141211


Type of Document Master's Thesis
Author Alcanzare, Robyn Joy Cabrido
Author's Email Address ralcan1@lsu.edu
URN etd-07122006-141211
Title Polycyclic Aromatic Compounds in Wood Soot Extracts from Henan, China
Degree Master of Science in Chemical Engineering (M.S.Ch.E.)
Department Chemical Engineering
Advisory Committee
Advisor Name Title
Mary Julia Wornat Committee Chair
Elizabeth J. Podlaha-Murphy Committee Member
Karsten E. Thompson Committee Member
Keywords
  • pah
  • wood soot
  • henan
  • polycyclic aromatic compounds
  • hplc
Date of Defense 2006-07-05
Availability unrestricted
Abstract
Polycyclic aromatic compounds (PAC) are organic compounds composed of two or more fused benzene rings. These compounds are ubiquitous in the environment and some are found to be mutagenic and carcinogenic. High rates of esophageal cancer in the Henan Province of China had led to the suspicion that PAC from domestic coal and wood combustion are the main cause. Extraction of PAC from wood soot was done with a Soxhlet apparatus using dichloromethane as the solvent and concentration of the solution using a Kuderna Danish apparatus. Analysis of the different PAC was performed by high performance liquid chromatography (HPLC) with diode-array ultraviolet-visible absorbance detection and by gas chromatography-mass spectrometry (GC/MS). HPLC retention time and UV absorbance spectral matches between sample components and reference standards present unequivocal identification of the PAC. Results showed that 84 compounds composed of oxygenated PAC, alkylated PAH, cyclopenta-fused PAH, and benzologues of pyrene, fluoranthene, and perylene were identified. There were a total of 35 compounds (3 oxygenated PAC, 5 methylated PAH and ethynyl-substituted PAH, 3 cyclopenta-fused PAH, and 24 benzologues of pyrene, fluoranthene, and perylene) that have never been reported before as products of wood combustion. Aromatic compounds detected in the GC/MS were 17 oxygenated, 14 methylated and ethynyl-substituted, and 8 nitrogen-substituted. Yields showed that 5- and 6-ring PAH dominate the wood soot extract. These groups represent the most carcinogenic and mutagenic PAH, specifically the C24H14 group, and comprise 66% of the total amount of PAH contained in the soot. The PAH with the highest yield are benzo[a]pyrene, benzo[ghi]perylene, and indeno[1,2,3-cd]pyrene. The high yield and the large number of PAC present in the soot suggest that the PAC may be contributing factors in the high rate of esophageal cancer in Henan, China.
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