Title page for ETD etd-07052012-110306

Type of Document Master's Thesis
Author Gilford III, James
Author's Email Address jgilfo1@lsu.edu
URN etd-07052012-110306
Title Microencapsulation Techniques of Self-Healing Concrete Properties
Degree Master of Science in Engineering Science (M.S.E.S.)
Department Construction Management and Industrial Engineering
Advisory Committee
Advisor Name Title
Hassan, Marwa Committee Chair
Barbato, Michele Committee Member
Okeil, Ayman Committee Member
  • Self-Healing Concrete
  • Techniques
Date of Defense 2012-06-15
Availability unrestricted

Recent studies in the literature have demonstrated the ability of self-healing processes to be effective in enhancing the overall life of concrete. The main goal of this project is to evaluate and to control specific parameters for the production of an effective self-healing matrix that can be utilized within the application of self-healing concrete. Therefore, the project objective is to synthesize microcapsules using dicyclopentadine and sodium silicate and to evaluate the effects of pH, temperature, and agitation rate on microcapsule morphology. The microcapsule diameter, yield analysis, and shell thickness were characterized using scanning electron microscopy.

During the experimental analysis, it was determined that temperature possesses a direct relationship with the pH for both sodium silicate and DCDP. As the temperature increased during the trials, the pH decreased. Temperature had a direct impact on the forming of the wall and core during the interfacial polymerization phase. Although the ability to maintain this consistency with the pH is important and essential, agitation rate is the key factor that controls the microcapsule capsule diameter size.

As the agitation rate is increased, the microcapsule diameter size will decrease. If the agitation rate decreases, the microcapsules will become larger. Sodium silicate, however, was not consistent with the normal parameter matrix, due to its alkaline nature. As the agitation rate increased, the size remained normal and consistent. This was due to the attempt to stabilize the sodium silicate solution for the micro-encapsulation procedure of Urea-Formaldehyde. Nevertheless, both sodium silicate and DCDP trials were successful in meeting the overall objective of this thesis, which was to control the performance parameters of the two self-healing methods.

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